Mercurial > repos > galaxyp > msconvert
view test-data/Rpal_01-mzRefinement.mzML @ 12:9ec469ff191a draft
planemo upload for repository https://github.com/galaxyproteomics/tools-galaxyp/tree/master/tools/msconvert commit ecdc3a64aa245d80dbc5487b2bf10a85a43adc6d
| author | galaxyp |
|---|---|
| date | Fri, 22 Mar 2019 14:18:29 -0400 |
| parents | 9d5de24e6ef7 |
| children |
line wrap: on
line source
<?xml version="1.0" encoding="utf-8"?> <indexedmzML xmlns="http://psi.hupo.org/ms/mzml" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://psi.hupo.org/ms/mzml http://psidev.info/files/ms/mzML/xsd/mzML1.1.2_idx.xsd"> <mzML xmlns="http://psi.hupo.org/ms/mzml" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://psi.hupo.org/ms/mzml http://psidev.info/files/ms/mzML/xsd/mzML1.1.0.xsd" id="Rpal_01" version="1.1.0"> <cvList count="2"> <cv id="MS" fullName="Proteomics Standards Initiative Mass Spectrometry Ontology" version="3.74.0" URI="http://psidev.cvs.sourceforge.net/*checkout*/psidev/psi/psi-ms/mzML/controlledVocabulary/psi-ms.obo"/> <cv id="UO" fullName="Unit Ontology" version="12:10:2011" URI="http://obo.cvs.sourceforge.net/*checkout*/obo/obo/ontology/phenotype/unit.obo"/> </cvList> <fileDescription> <fileContent> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> </fileContent> <sourceFileList count="1"> <sourceFile id="RAW1" name="Rpal_01.RAW" location="file:///"> <cvParam cvRef="MS" accession="MS:1000768" name="Thermo nativeID format" value=""/> <cvParam cvRef="MS" accession="MS:1000563" name="Thermo RAW format" value=""/> <cvParam cvRef="MS" accession="MS:1000569" name="SHA-1" value="4677b1f0c0556933ee113c7712164c37087bfb24"/> </sourceFile> </sourceFileList> </fileDescription> <referenceableParamGroupList count="1"> <referenceableParamGroup id="CommonInstrumentParams"> <cvParam cvRef="MS" accession="MS:1000449" name="LTQ Orbitrap" value=""/> <cvParam cvRef="MS" accession="MS:1000529" name="instrument serial number" value="Slot_81"/> </referenceableParamGroup> </referenceableParamGroupList> <softwareList count="2"> <software id="Xcalibur" version="2.0 RC 2 upd 060213"> <cvParam cvRef="MS" accession="MS:1000532" name="Xcalibur" value=""/> </software> <software id="pwiz" version="3.0.8688"> <cvParam cvRef="MS" accession="MS:1000615" name="ProteoWizard software" value=""/> </software> </softwareList> <instrumentConfigurationList count="2"> <instrumentConfiguration id="IC1"> <referenceableParamGroupRef ref="CommonInstrumentParams"/> <componentList count="3"> <source order="1"> <cvParam cvRef="MS" accession="MS:1000398" name="nanoelectrospray" value=""/> <cvParam cvRef="MS" accession="MS:1000485" name="nanospray inlet" value=""/> </source> <analyzer order="2"> <cvParam cvRef="MS" accession="MS:1000484" name="orbitrap" value=""/> </analyzer> <detector order="3"> <cvParam cvRef="MS" accession="MS:1000624" name="inductive detector" value=""/> </detector> </componentList> <softwareRef ref="Xcalibur"/> </instrumentConfiguration> <instrumentConfiguration id="IC2"> <referenceableParamGroupRef ref="CommonInstrumentParams"/> <componentList count="3"> <source order="1"> <cvParam cvRef="MS" accession="MS:1000398" name="nanoelectrospray" value=""/> <cvParam cvRef="MS" accession="MS:1000485" name="nanospray inlet" value=""/> </source> <analyzer order="2"> <cvParam cvRef="MS" accession="MS:1000083" name="radial ejection linear ion trap" value=""/> </analyzer> <detector order="3"> <cvParam cvRef="MS" accession="MS:1000253" name="electron multiplier" value=""/> </detector> </componentList> <softwareRef ref="Xcalibur"/> </instrumentConfiguration> </instrumentConfigurationList> <dataProcessingList count="1"> <dataProcessing id="pwiz_Reader_Thermo_conversion"> <processingMethod order="0" softwareRef="pwiz"> <cvParam cvRef="MS" accession="MS:1000544" name="Conversion to mzML" value=""/> </processingMethod> </dataProcessing> </dataProcessingList> <run id="Rpal_01" defaultInstrumentConfigurationRef="IC1" startTimeStamp="2006-10-20T18:27:59Z" defaultSourceFileRef="RAW1"> <spectrumList count="102" defaultDataProcessingRef="pwiz_Reader_Thermo_conversion"> <spectrum index="0" id="controllerType=0 controllerNumber=1 scan=1" defaultArrayLength="117"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11918620901406" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="9970.462890625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.5247459375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="413.26507380032433" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1683.2779848897426" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.1.1. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=1""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.009243333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="255.819259643555" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="612"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="316"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VBpSxVC1UwZC9iVOtWmlMTVQpeNVijXANRbV50UxddVFd/XEVO5BXndSA19lX+JUXlDUV/JRSVoDW4Vd81x0V4NQ1FdkU8Vb410WVGNX81TSXXRaY1YnXBNW01IUVqRY81RjUaNRI1nUVCNe8lYzVWReg1yjUjRWdF6jW3RUk1SkWMNb81PjWgVdRF/yWARXQ1rTVsNQk1wUVgRcs14TUkReZVNzWkNUc1qzWGRdw13zVERWw1FTXpNTY1jzXjRWs1qjWYRVg1yDX/Nbw1BkVLReY1J0XONU81DDWtNTRFTkXpNd015EXdNWFQ==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="1" id="controllerType=0 controllerNumber=1 scan=2" defaultArrayLength="18"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="429.08813920351855" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.1581103125e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.77712703125e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="124.03110562505753" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="430.08929154784141" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.2.2.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=2""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.040338333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 445.12@cid35.00 [110.00-460.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="445.11915569163494" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="460.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=1"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="445.11674970150455" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="445.11915569163455" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="9970.462890625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="112"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXBRglAAAAAH0X9+yP//fwQRgTQwsVp8zQ2CqL3gZPsRAZi7NoWTEEdNDhE0/kD2sXRtDdvYuNEwX6TJp4aLaZR538COfy7REn9G1gWllQza5oME</binary> </binaryDataArray> <binaryDataArray encodedLength="52"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V3JbsVThXtNQUlyxVcFdjFpyRt4lerWYNQWVXSUmJbxDNkwUqhg=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="2" id="controllerType=0 controllerNumber=1 scan=3" defaultArrayLength="24"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="281.05095308462217" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="17159.619140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="54723.9296875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="131.57366824743067" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="504.10545278878044" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.3.3.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=3""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.083275" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 519.14@cid35.00 [130.00-530.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="519.137726884215" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="130.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="530.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=1"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="519.1363084392151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="519.13772688421477" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="5357.81103515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="144"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW3B9UAAAABwlVp6pv//fwKmbNAwz/9JnA1QmlAZNP8zAUG7gSJ0+7YqgQTA/QSO8gFYCB3ChYkMHbYEfAbpGcsQACFjnR/TnXYCeGMkID2NSp0cAOJ9CiwvQhCHIUvdEcgGGpfR/BOUueze</binary> </binaryDataArray> <binaryDataArray encodedLength="68"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XMFfwVVjULNXAlrBVeFfo1mxSANFQaUNFY/laRVxJT8VexWeJT8VTiVhJS4UD8NBEhA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="3" id="controllerType=0 controllerNumber=1 scan=4" defaultArrayLength="27"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1223.575093877565" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1153.5234375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="16781.51171875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="137.91694459889658" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1282.657673263257" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.4.4. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=4""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.13051" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 486.63@cid35.00 [120.00-1470.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="120.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1470.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=1"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="486.62651546906574" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="486.62651546906574" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3959.364013671875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="164"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWlXDyAAAADymjZt+v//fxDTcKgIjrek4ycqMZc0jXpPIRwLfxmPIMhUFC0J8PdqEObDGk6Yzb+rHTvS7JoB0JYHyen+GUBSVZCb3jpeAERKehnEHWmw3xaRpAdQOTCgx2CfsQ8Xnv9Q++TYjAz/2SHQ7I9lpwM7R8iQ</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>W+FY4VriUJJc8l3xUcFVsVWhVsFYUlviWLJe0VzhXRNfslXxUJJRo1fCXCJe0VfiVCJShFBC</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="4" id="controllerType=0 controllerNumber=1 scan=5" defaultArrayLength="20"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="519.13766584957636" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="6786.09228515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="34540.7265625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="151.69946706777623" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="520.13814564204893" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.5.5.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=5""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.177011666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 536.17@cid35.00 [135.00-550.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="536.16407095783018" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="135.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="550.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=1"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="536.16616322505149" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="536.1640709578304" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3668.349853515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="124"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWYmhgAAAAARuwFp9v//f5XG2+CdAOEbFPIjhZOORC2VS3csBWbDABGr96FAiIp8rhDwdtqd8Ti0GA4p8Qp2Dn0Q9Md3ngcDuqhAoXTm65YMKmAQvAa5kInpRg==</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VeFfkVwKX1JXsVuiXrFdgkY0FV81ShXERekVTxV7FTokxoFeukKKFdmg</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="5" id="controllerType=0 controllerNumber=1 scan=6" defaultArrayLength="22"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.35082805547177" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1107.370849609375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9689.80078125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="179.36311357916469" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1434.8431103055505" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.6.6. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=6""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.22351" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 479.57@cid35.00 [120.00-1450.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="120.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=1"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="479.5665503521717" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="479.5665503521717" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3425.3310546875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="136"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTe3KAAAACmQvt0W///f5Nf2gUWZDjpmBhHVx2UMhIA2XJ8EH4r8v6YRujDAQXmHjB6GJBsF0x+ShLIoGgEn8gs6UOOYbEIOKsQXAkHAQVy0SBgZkwiZQbODU2Q7TFiXAY/tg5Q</binary> </binaryDataArray> <binaryDataArray encodedLength="60"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VsFe8VNUU0FeUV5RXDFWQVpBVkFTQVpxVUFe0VhhUyJZgVRxVwJZkVRTVFE=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="6" id="controllerType=0 controllerNumber=1 scan=7" defaultArrayLength="168"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11967448707202" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="57457.40234375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="3.74361875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="411.36210310182707" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1522.9956970044836" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.7.7. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=7""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.266041666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="289.812835693359" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="852"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="460"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>Ux9NliUGZaKVFEWQ5ShFDyWmZAziRt0V2uUMVeU1FmU5NFgBUzRQ1UFw5NmEQXEltEUcdVhFVUURNFGzUnRVDloJUD1Y8lUWUhtfVVmGXJhShkBSFRc1KzUNJJaUTNoU/gFclFQVW0pPMDRUIVLYXfVYdFCjWcRbRFKmU5hUE1UDWA1TZVK1UthZ/1wWVwRRol8lVeJZM14EUPRX419TWtVYdlsHXyNaM1UjXLJXBFBEU6ZYol2iVXRTE1dDWlNfU15EURRUY1ZzUxNSA1xjV0NSw1NzVINUE19TXkNWQ1NkU4Nf81c0VTNUc1wzUbNWo1EDUjRTo1rTV2NelF/DUGNYg1fDXhRd41gTWSNXk18DVLNQk12zVVNao1UzXnRbY1izUgRVs1dEXZRe01XjXTRcY1kkXjNfo15EXdNe81izVnNcc1WjXuNTo1YkXPNcY1Q0VKNRNg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="7" id="controllerType=0 controllerNumber=1 scan=8" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11939983066355" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="26064.45703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="50098.75"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="122.42266554788299" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="446.12040036849828" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.8.8.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=8""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.299675" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 462.15@cid35.00 [115.00-475.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="462.14596138212244" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="115.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="475.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="462.14663886796745" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="462.14596138212283" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="15125.09765625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXCLrOAAAACO6ph+uf//fwSNhUEZneLacFfd8YEAgrEZ4W7LjkFAtT2Bm1SdOdUxN6kHpxyQbV66/qC9D3Fdo4IgvMpbsZahlaQJOQhYMB0U2lsezNV8mg78hJEPHf4=</binary> </binaryDataArray> <binaryDataArray encodedLength="60"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XsFZQlHhX+FSoVG1V7FQAlHhVsFTEljBVTJYoVehXFJXv1f0V+JA1WS/Mg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="8" id="controllerType=0 controllerNumber=1 scan=9" defaultArrayLength="35"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="341.01764698363104" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="92341.8515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.59381390625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="105.30799124592053" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1113.1123689962385" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.9.9. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=9""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.34501" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 429.09@cid35.00 [105.00-1300.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="105.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1300.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="429.08686113669586" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="429.08686113669586" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="11968.4345703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="200"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVxYlMAAAADmP6Qu+WS+MJZ1VT4TZYPqmtP2vJ4mrA0bH67YlrSqqZXJ4IyjLqnawY8tHZC0Whfs8cKfm5azEkKeRZCTGKap5yXqygYsH/VvNZC+aGyTypC+FcSi0Rgf66Whw0kZTU4J2RBWlMBQqDcCD01mmuCEdeAxBEcnG+lva9vAt2h7cQIczsTgS7JvgQdlIz9w</binary> </binaryDataArray> <binaryDataArray encodedLength="100"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WyJaAlThX7FfkVHxXWdZwVICXqFW4V6hVBJTkza4YUB4VW4VADUrJJz0TSYVfhWgJf4VADXPFTslgSVrFWkVVyVrJUQlvxWvEA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="9" id="controllerType=0 controllerNumber=1 scan=10" defaultArrayLength="19"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.34885968608182" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2186.26220703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="13113.005859375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="102.59752370785451" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="344.97452721788227" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.10.10.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=10""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.39151" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 413.27@cid35.00 [100.00-425.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="413.26586725155141" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="100.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="425.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="413.26697686257501" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="413.26586725155101" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="9885.3359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="116"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXL7eOAAAAD6nLh5zv//f5zudlsf8qpIlEa5ex0gDVUBuXrQEdslJ1CEnfSOmYEV2pdeF+4Pebv1QKLMjvspaFcp6DmLwHfOVlGbgSzbnpc2YBVzyN0=</binary> </binaryDataArray> <binaryDataArray encodedLength="52"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VsFT0V+CWpFegV6RWcFSElnhU+FaiFihXuFa4VACVpZX4VP1WSI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="10" id="controllerType=0 controllerNumber=1 scan=11" defaultArrayLength="18"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="281.05104463668744" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="26649.548828125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="52947.421875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="147.17412480542382" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="488.75828351487382" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.11.11.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=11""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.434455" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 503.11@cid35.00 [125.00-515.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="503.10680139850871" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="125.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="515.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="503.10641932066449" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="503.10680139850859" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="4688.15380859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="112"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWaegCAAAAC7ngdobv//fwrND5vhSV6pOSO37YHIh54pjLae4a06mqCibV3RBP/BVtEC4RW5lMD6QZV0CxDYj3KBCERkyRDlbjbMBEWn7yAlAMIt</binary> </binaryDataArray> <binaryDataArray encodedLength="52"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VeFa0VThV4RUAlRiXaFcJUoYZLYBSNcVz1XEJYZltvVRZVI1WxA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="11" id="controllerType=0 controllerNumber=1 scan=12" defaultArrayLength="12"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.34725752494998" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1882.517944335938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5734.54541015625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="140.46276337802493" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="412.46609893210848" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.12.12.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=12""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.478233333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 439.38@cid35.00 [110.00-450.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="439.37804337801009" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=7"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="439.37678728273085" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="439.37804337801049" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="4229.0107421875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="80"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWsZSCAAAAAb7vJ2xf//fwyvCT0RoShMEMVeq/0T8siXlm0dIxpPhD+RSIgXqUKncDCiwxMO81lP0A==</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UGFeQVtXV4FaIV4hU6FdUVwhWXFSYVhx</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="12" id="controllerType=0 controllerNumber=1 scan=13" defaultArrayLength="215"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11976603920743" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="83188.8359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="4.87288125e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="409.27154222285759" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1522.9668886629954" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.13.13. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=13""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.524958333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="362.855773925781" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1052"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="588"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="13" id="controllerType=0 controllerNumber=1 scan=14" defaultArrayLength="10"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="355.06960717878036" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="6985.35400390625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="12296.525390625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="189.55945012356693" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="552.90964385791199" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.14.14.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=14""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.560175" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 593.16@cid35.00 [150.00-605.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="593.1569212096822" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="150.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="605.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=13"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="593.15554427388543" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="593.1569212096822" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="5153.9130859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTZ/sAAAABa24R7vf//fw+ZOlcQLiQ78g8G9TWwQKTCEwU7Sozgjo1CbgYdN1MgS7/kvQ==</binary> </binaryDataArray> <binaryDataArray encodedLength="28"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WbFYo1XxSUsVHhUkJaA1uSWLFZ4Q</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="14" id="controllerType=0 controllerNumber=1 scan=15" defaultArrayLength="18"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.34112353661843" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2644.397216796875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11062.095703125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="117.1333136766733" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="449.11244626358086" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.15.15.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=15""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.603096666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 467.41@cid35.00 [115.00-480.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="467.40914812401348" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="115.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="480.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=13"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="467.40661151582151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="467.40914812401371" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="4607.11865234375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="112"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW9eB4AAAACGP9Fy8f//f5BqlxUaBq42kgLAXZB4Ap4DDxgCGbiBbSGC6gcpqxs6UJNWlIIMcOqK0ePHsoDeHWYzBxtFQMEmNSFQf0mIc5Tv7B4=</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>X5FdAlASVaFXkV3RVAJRkVRaVMFWQljBVPFTkVOBUBJXMlVT</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="15" id="controllerType=0 controllerNumber=1 scan=16" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="355.06899683168223" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="4473.37646484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11696.07421875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="160.83039697714776" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="539.50290817985524" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.16.16.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=16""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.646795" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 610.19@cid35.00 [155.00-625.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="610.18435336981361" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="155.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="625.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=13"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="610.1853274783648" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="610.18435336981338" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3328.767333984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTfOIAAAAB0wuZo8v//fwSD9vjgRBIloQ9/G/Awiqema5DVL94TBvPEDR4KjiDW/i1+FAu0tg==</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>URJfYlzmX+FdEklxFfZFXRUcFXglEyA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="16" id="controllerType=0 controllerNumber=1 scan=17" defaultArrayLength="24"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="430.08929154784141" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="62657.1171875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.42655140625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="125.45525902542703" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="433.08518027679759" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.17.17.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=17""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.690561666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 448.12@cid35.00 [110.00-460.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="445.11979655658598" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="460.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=13"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="448.11673010479257" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="448.11673010479257" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="27666.529296875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="136"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW3gFUAAAADhISB1l///f567+RoNscRLGQO8DBDICmHuAJVGDhAprRZeo8n/WXI1GNK1RHoJIgmxIIDLO7ECpOHRwmFNRiKbw0EDp0/p0QSPIci2j3C3Bo9yAY3DLsy8UENQzNWo</binary> </binaryDataArray> <binaryDataArray encodedLength="68"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VBJQIlDRVfFWQlnlVHJeElaxU6FQsVmRWxVf4VNeVRxWol6hUfFffEHE9Lm6TzI1MbA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="17" id="controllerType=0 controllerNumber=1 scan=18" defaultArrayLength="16"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2100097253244" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1519.226928710938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="8238.27734375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="346.20147747099151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.171251958262" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.18.18. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=18""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.737678333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1223.44@cid35.00 [325.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="325.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=13"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1223.4290355395221" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1223.4290355395221" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2737.40625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="104"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVNIwUAAAABW31Bo4v//f5BN8eoY8ww0GxTxlBYqcFMHlPC14T37Z7FRA7qAt8xZYgcSq0Lgm3PkYxSr3YILgEQmoNd86eEGaO1H4A==</binary> </binaryDataArray> <binaryDataArray encodedLength="44"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WFFaYVjhUjJTQVlxU2FRAlyBW3FcA1qBWzFbYV/lUQM=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="18" id="controllerType=0 controllerNumber=1 scan=19" defaultArrayLength="169"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11958293493552" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="44387.046875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="3.1440665625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="405.29940331116387" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1522.9994811510355" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.19.19. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=19""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.780018333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="314.358581542969" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="852"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="460"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VyRcmEYxNVs1GrXXRaA1PuUGNYpl/jR6QlpzQigVkIXyVYZ1G4V/VXNVFFX2lDbaTMwl2DTksVLmUKZVhFVyRj8lRaX1dRFVqIWTRRNVA4XNJQ4lg8XgNQdFLjR+g0JEFcblo1VHNfIlEyVHRR4lJURvMlwJUFlbk1gzXWJXBFAEWZJQiFhiWB1WpFmWWGVXqlB1UnJZU1cTVsJZZFbDWQNdRFTiXTZdslwzVeNQI1oUWANRklfSWuJfglczXLJTE1kTXsJaM13DUyNQ4luiUaJZN1kzUFNeslQDVsNT4lYTVMJfwlQjX/Jdc1KyXANQE1azXUNf01/zWtNfY1ODWgRV4lojVVNQU1TyUjNc01ILVSNewlZzXBRYI14kUVNTA15TU7JYA1mTWNJQs1KTXJNWo1tDW9NSY1kFViRXQ13DVehVKF5zWXNQw1oEUrNYo1JjXwNc5Q==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="19" id="controllerType=0 controllerNumber=1 scan=20" defaultArrayLength="28"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.3340740276401" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2821.30029296875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="18057.02734375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="110.10904255097161" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1209.7954301351638" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.20.20. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=20""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.813671666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 419.32@cid35.00 [105.00-1270.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="105.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1270.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=19"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="419.3169326058387" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="419.3169326058387" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3810.67041015625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="172"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWpBpAAAAABPi1ha9czDaJM0z/iZ7RG8FQRP0RCxILYfZ8p9CFTBK+FjJeURXwpTiUB3UEFzNx7Ax9M68gfhliXgU6W4HhgS/JEEhyhOEMjatf0LgkXcEA9xBf0PiUjWMByHE+IELVPxqUkSC9BzXTH3CnzWnOAD+DKOli/eyA==</binary> </binaryDataArray> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XeFd8VWxVNFUQ1qhVQtT4VTxXVJe0VASVUJSsV7RVeFbAlvRVIJfxF3RUEJSkloCVdFWY1FCWdE=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="20" id="controllerType=0 controllerNumber=1 scan=21" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.3061384724335" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1927.568969726563" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9375.111328125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="484.83459800966165" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.3060164031895" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.21.21. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=21""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.858846666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 999.23@cid35.00 [265.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="265.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=19"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="999.22098322588249" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="999.22098322588249" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2817.986083984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUjcpgAAAACJ0yteNfyEXg0JmHEQEPty8g1tDc/BNs7wqZP1vVk4MNUq7T6QDcgzv3DJ7+Qo</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VCNVE1nxVdFSklXxVjVTIl2xVHVYhw==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="21" id="controllerType=0 controllerNumber=1 scan=22" defaultArrayLength="17"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.33024409960285" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1664.823852539063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11190.8193359375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="139.19116623472038" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="999.25685195383937" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.22.22. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=22""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.901763333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 475.24@cid35.00 [120.00-1440.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="120.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1440.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=19"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="475.23657197474535" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="475.23657197474535" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2186.156494140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="108"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QV4eHgAAAADQcIBBwgRkXAzP5yXhbfcFEH2dXAMPWaUb0cx2dTDASx2RBhyvntlgJplxZ5iLIPSb2sEG/8OD4EFZBMcGClOwgC2Do6KWqbgY</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>U+FRhl9iXKFaklYCUYJT4V7RW9Nf4lkiVgNdwVkCVwJQgg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="22" id="controllerType=0 controllerNumber=1 scan=23" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.33006099547333" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2334.31005859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="14513.552734375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="140.44979350219938" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1659.0844711556877" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.23.23. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=23""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.945383333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 562.07@cid35.00 [140.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="140.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=19"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="562.0659226601872" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="562.0659226601872" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2175.73583984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVNGeYAAAADC10wqvK1pMZktg6ocwtY2mWcs6ZQIeX4IYggAGed8hFm74nmx68KEgXoJpCk+uSZhBbYHgdzmLOCTGDuOCV5y6BG4NapgxGcJ9wLFy+iw1jVS65KdWGg=</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XIFfwVfhXhlf8VgCW+Fc4VXRXbFQ8l5SXcFRA11DXqFREl7GVfJS8VIC</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="23" id="controllerType=0 controllerNumber=1 scan=24" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2043945401192" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1925.99462890625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7276.74609375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="215.84406314378302" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.2360707266107" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.24.24. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=24""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="0.98903" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 785.34@cid35.00 [205.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="205.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=19"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="785.33340250990977" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="785.33340250990977" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1849.05029296875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVXJiAAAAAAHlHpJv4SASw1fC7VQ+gCgqgAtO5BwfpahqwJEypfgnGpFQwWzjI0QGcWYAgcw8qCA</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>X1FTQV9yVHFccVpRVLFdol1CVodexA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="24" id="controllerType=0 controllerNumber=1 scan=25" defaultArrayLength="202"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11976603920743" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="86080.3515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7.49202375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="401.34227893807252" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1671.9976881584919" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.25.25. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=25""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.032328333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="279.505950927734" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="996"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="564"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="25" id="controllerType=0 controllerNumber=1 scan=26" defaultArrayLength="18"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.33181574337894" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2109.204345703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="12742.88671875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="180.51166474757619" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="659.6396671576" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.26.26.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=26""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.064673333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 656.59@cid35.00 [170.00-670.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="656.58189413456819" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="170.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="670.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=25"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="656.58485797533842" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="656.58189413456864" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="21275.8125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="112"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWZQ6oAAAADYf+J9hf//fxT0MqWRUXtplahV7hiLgOIYOCJCBqljhCCwaZKOlX1KtgjCynFQ3G3eigfsBNcQ0peVbhn4hnIFlY8YMFFo2n6Vr003</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XsFUUlNCXThaUltSUhJYIlACXDJZ4VsmXNFTUltTUCJQ8VpC</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="26" id="controllerType=0 controllerNumber=1 scan=27" defaultArrayLength="31"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="429.08801713409849" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3148.640625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="26127.35546875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.23025398632521" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1989.0420310822547" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.27.27. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=27""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.11101" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 684.62@cid35.00 [175.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="175.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=25"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="684.61461726431151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="684.61461726431151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="10590.533203125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="184"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWBBBAAAAAA5KaxjJ8a4YxrDlCIUo59zl7QAiws2cBERa3iH0M/l7p6aOnArGh4LUiqySqBuwUFBCWMGBumtuKnhVIZjyT1tC7q7MKIMona+MNv/4C4K7/Td6bhvO8HScpzgbWfGYQtxtV7Z+f9lADeZLgYOEnoPcNP2NzkEb/aAkf4nEcDexT2+</binary> </binaryDataArray> <binaryDataArray encodedLength="84"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WCNXV1cyWoJeElIyW2JSwVBUUlJZ4VLRXUxbs1XRVeFSQ1MSWSJU0VKiUfFT4VUiWBJYBFgSWbdc+FGSWsI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="27" id="controllerType=0 controllerNumber=1 scan=28" defaultArrayLength="18"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.32621580875769" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3069.898193359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11231.90234375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="127.43826911644581" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="495.85778995888006" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.28.28.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=28""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.157343333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 495.44@cid35.00 [125.00-510.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="495.4401898771265" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="125.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="510.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=25"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="495.43646431311555" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="495.44018987712701" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="9626.736328125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="112"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWqcl+AAAAC/yPppuP//f5PGGXeffe6KH3k1dJoTJLQWXirBEMWnNxGA3AEXR3dqDg6B/eCnyGtSBNjU0jBR8jOcCcUE6tGpUibpQc8EcTTsfBA=</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XeFegV2xW6FRAl77VrFeIluhXdFSEltiXZFewV/xU/Fd8Vyx</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="28" id="controllerType=0 controllerNumber=1 scan=29" defaultArrayLength="14"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.32340821210886" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2908.99365234375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="10078.01171875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="160.62676992668472" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="507.10354320783659" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.29.29.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=29""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.200306666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 523.48@cid35.00 [130.00-535.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="523.47191858733242" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="130.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="535.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=25"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="523.47627157765407" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="523.4719185873322" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="6582.52294921875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="92"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWg/ksAAAACDc7d5wf//fxOb+sSc9cwVEFz/SRu71wIdzP/yFbV+LghLBFzpWVK9gO+jN1EO+zvXIBauRDEKXEhOoA==</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UnFQsVnhW9FdW1rhVcFRwVzBU+JYsVICUORQYg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="29" id="controllerType=0 controllerNumber=1 scan=30" defaultArrayLength="16"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.32200441378396" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1675.816528320313" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7867.40087890625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="159.68697272435674" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="533.1825901439546" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.30.30.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=30""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.244005" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 551.51@cid35.00 [140.00-565.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="551.50255251582576" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="140.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="565.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=25"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="551.50602172170397" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="551.50255251582598" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="6265.06201171875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="100"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWYDOoAAAACoBNltxf//f5pPdeSSkevrGbu9gxmZFAGpiIW5yyRo0VuaqBDJZTKUBasV0bGHUocQCZJvIiUFzIC4TmntBlhqKxA=</binary> </binaryDataArray> <binaryDataArray encodedLength="44"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VzFZIVyGWJFeYV6yWyFSkV0xVjFaYVcCXpFUsVxyW5E=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="30" id="controllerType=0 controllerNumber=1 scan=31" defaultArrayLength="200"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11976603920743" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="65402.6953125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5.522780625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="411.17164428999547" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1683.0406822801965" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.31.31. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=31""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.290793333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="217.295623779297" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1000"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="548"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="31" id="controllerType=0 controllerNumber=1 scan=32" defaultArrayLength="20"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="365.10526984971881" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="6526.39306640625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="20026.966796875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="109.25412174191446" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1223.4521701099634" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.32.32. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=32""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.320343333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 423.07@cid35.00 [105.00-1280.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="105.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1280.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=31"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="423.06690517397732" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="423.06690517397732" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="5539.5390625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWkg+0AAAADnbctVNze9WwGXcEcQ2X9//pjZ0L2b7kxKn2Wm7qojFlAtS8MCD5GmQTDXO/y6GZ6AN5qNMugG8gNKQChz3ywH3g6yEC1nJRUP/k6moIJK3OcDI99NYA==</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WDJQ0VjBVAJZoV3BUptZgl5SWwJQ4U55FVQ1rRW7JZwVPRU7JZMlqkA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="32" id="controllerType=0 controllerNumber=1 scan=33" defaultArrayLength="27"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.1749758524136" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2913.959228515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="18097.1640625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.31994449232872" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1985954688269" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.33.33. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=33""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.36551" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 690.58@cid35.00 [180.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="180.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=31"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="690.57455967655096" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="690.57455967655096" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2918.89697265625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="160"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVGxfEAAAABAMUY2ZZDiNyqJh0nH8yjgp5MI0QqxRNPhF73+ad5JVdmyrpTgAtF4MZXTzf6XWQFzk5Qmaho82pudp7VJDG4E1CCqG2XOBQ/BfOmy1ffhS29fMeXysjlgectAHUt49wqKicC5J04XQARQ0h6clX9e</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UmNY4VRSV5Je0VXxVbJZ8VMCUkNTMlPhVrFUIlvBVgJW8VUDUjJf0VwSVRJXMlkSVAJSa1ME</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="33" id="controllerType=0 controllerNumber=1 scan=34" defaultArrayLength="13"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2861809333269" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2418.442138671875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11440.837890625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="515.19147125298002" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1662471192751" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.34.34. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=34""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.408293333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1522.94@cid35.00 [405.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="405.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=31"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1522.9266644058466" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1522.9266644058466" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2540.958984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="84"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUe5cYAAAABxNH1fsP//fwKhAuDgdXamYwtP0lzRf9Q0EODAQiIB0ppd0MoJ2d4b9yKMEjpvARbT57KewbMR</binary> </binaryDataArray> <binaryDataArray encodedLength="36"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VxJR4lfiVINbAlZkU3NeElMCXvFeAlJ5W8U=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="34" id="controllerType=0 controllerNumber=1 scan=35" defaultArrayLength="13"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1223.1949701315198" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1423.935424804688" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="8259.25"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="380.15078356782499" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1982.4111077010002" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.35.35. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=35""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.451741666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1356.09@cid35.00 [360.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="360.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=31"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1356.0780416157959" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1356.0780416157959" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2083.30712890625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="88"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVEU1IAAAAAf+3VlPv//fwHN1lfh4cBl2elzS1HpLISwk1YpRQsQEwaxaJd+UEK3fSUOfJl2kEPtCXME4fH5wA==</binary> </binaryDataArray> <binaryDataArray encodedLength="36"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XKFT0liCVnJQUlwiVFJWsVCVUQJQclRSXOE=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="35" id="controllerType=0 controllerNumber=1 scan=36" defaultArrayLength="20"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.31442085109535" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1558.97021484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9070.7607421875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="174.45357307750061" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1866.5620244838515" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.36.36. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=36""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.495416666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 624.24@cid35.00 [160.00-1885.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="160.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1885.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=31"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="624.23517158512504" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="624.23517158512504" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2080.5927734375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="124"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QV1B1AAAAAAdDcBPnmfFTywdnUGM0DWZaP5YcelScMmCeVuQB3bRwQ47zLjhbd9yoGYgaRGb+YjFD/0FSOlFBhCwKJnnw541DewLQuKPcLRoqPyYJolLAMdQdJA=</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>W2FWYVZBVxZVMVmBV0FYUV1xXkFW8V1hWmFRUViBWnFeA1zBWZFWgQ==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="36" id="controllerType=0 controllerNumber=1 scan=37" defaultArrayLength="239"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11976603920743" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="29450.361328125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="4.52970625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="409.27077928898456" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1695.0045667755728" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.37.37. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=37""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.538611666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="267.736206054688" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1192"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="652"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="37" id="controllerType=0 controllerNumber=1 scan=38" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="391.28415549393952" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="7730.91259765625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="22501.90625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="111.57042712429902" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="392.29012958033326" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.38.38.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=38""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.571171666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 436.34@cid35.00 [110.00-450.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="436.34174825117253" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=37"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="436.33680810176389" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="436.34174825117265" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="6230.8671875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="132"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXIaToAAAAAkuTt+2v//fxp2mRQJYv/cEGwNHz6YOys8FvzzswUU7Y4Q1PfurQHY5hIQngZ/Qg+/jrTZR+ilqeiZU6FhN1QQTs8iAZLZW2qTPMjbA7dmYFBxVS16KD1YYA==</binary> </binaryDataArray> <binaryDataArray encodedLength="60"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VbFawlXRWiVfsV3RWhJUA1I3UPFUFF3RVBJS4VRzXMFXUl+RQz4VHxXEcA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="38" id="controllerType=0 controllerNumber=1 scan=39" defaultArrayLength="24"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2363766819408" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3044.093017578125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="20332.41796875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.22143447076385" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.3080915803309" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.39.39. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=39""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.617513333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 676.08@cid35.00 [175.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="175.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=37"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="676.07468994895135" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="676.07468994895135" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1975.133056640625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="148"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWGnuWAAAAABlkJsMNhPbBbsK5cfHWCSkIFxmggvoFwgiDdV/Z6fYXYELlxGMCVWu1yZQnAeG3AlgQV4DqwwQQ0FtAWe8wGBfbpFUMwgtxKQpZSAAKPq5TBqpvflC5lozIADJYZcDbGyQXA7ks4J</binary> </binaryDataArray> <binaryDataArray encodedLength="64"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UBJZmlUiWrFT4VDxXdFXoVyzXLJSwlHRX/FYQlThXyJfY1HhU4RXAlRSWXJU616X</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="39" id="controllerType=0 controllerNumber=1 scan=40" defaultArrayLength="25"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.31419197093368" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2630.817626953125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="17423.05078125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.31420722961104" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1252318534275" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.40.40. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=40""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.660341666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 758.23@cid35.00 [195.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="195.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=37"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="758.22369823445956" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="758.22369823445956" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1918.886108398438" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="152"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVrFcAAAAACZTB5Sw/hEWhIjkbMdKqqTlJAq6pzXQUkLv95CGVnG5plWo7NBeCyK2fih+pmYp67hb2Ut4AnG0EEIkqxM2R82L3AoWtL3BbE1PIGcK17heJvF8HhAXg4LsliscGqlM+gLrRJ9UBTlVFo=</binary> </binaryDataArray> <binaryDataArray encodedLength="68"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V0pYIl7hUGZaolDBVOFQwV+xXsFWE1eDXPFWElSyUgJWg1pCUwJY4VPCWsFU0V0iWQI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="40" id="controllerType=0 controllerNumber=1 scan=41" defaultArrayLength="25"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.31263558583396" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1566.7802734375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="14223.4453125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="135.92825065052944" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1378.122503274672" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.41.41. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=41""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.704146666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 509.46@cid35.00 [130.00-1540.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="130.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1540.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=37"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="509.4563822961797" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="509.4563822961797" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1895.388793945313" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="148"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QV1crIAAAABMgVw+TKidTpx4OCqf4CCmptthATWJThqE0kUdH+toHwfQFBj1zvqZ/AtDCrHJihmFk2gg6CJLnqrEl5lLbAfhRlanMJFC2rQCljEosCP2LIEB8/2KGXTS+TDmJcRNCks8P3BsVlqK</binary> </binaryDataArray> <binaryDataArray encodedLength="68"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WEJfIlXhXxZZslMSW5FXsVmBUhJX0VnxUNFQAlAiWUNdsVuxUsFc0V7xW/Fe8lQiUiI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="41" id="controllerType=0 controllerNumber=1 scan=42" defaultArrayLength="20"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2349118510176" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1899.230102539063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="12198.6005859375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="185.15144709074363" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1292601384657" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.42.42. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=42""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.747696666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 712.65@cid35.00 [185.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="185.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=37"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="712.64432019148626" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="712.64432019148626" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1658.708251953125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="120"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVXJiAAAAADuvwc/cF/UQppaazwaIhpun4/btSjjLVGGyp9RmAsAED1BaDILMP+U2h2YQyrSnxEssJJAsSVBsQFJHhMpy/dvcVXKhuCBGeShA649cCDi3WkI</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VFFQdV+RUmFSYVNRV1FaUVfBWVFZkVuCV2FSoVSxVGFQkloCW2dShQ==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="42" id="controllerType=0 controllerNumber=1 scan=43" defaultArrayLength="218"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11967448707202" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="34327.4921875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="4.4119984375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="401.33846426871162" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1699.5057480638472" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.43.43. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=43""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.791013333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="233.244079589844" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1092"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVRRnoAAAABa52p//P//fxC6MwKT6OhtKEwwW4HsehOs+zj3JiNAGiKiBoqq7IhzPsBC7AQtL4alGfoMDerrvK4rWjmKhYYYvExeJyyPKo8VLSSK1yrYZr09ceUUxv9xkbTrviImk1qctsqtnhjihT7GuSBKoJ0jch8zkiHswxq3uhwoW9sqvrhcGI4sZJ2Qbqsga+MRJ85yGXA+b+rrrc4beouRlJz4PhYFu0GZu4OuEwgnoZlU6u6plz/B9Z1QKXT7bemI633ivl//osyZPMA8Ec7TJJSRnNvIfnIAnsYXYihSnYnr3aYhj1x8KR31EnEuS91Jj5d16sYCnh3NUpKuJCDpIl354gQ9nyGJmIkGFCva3V2LGH5FxJeV6jvAgCFTKhLJG1gZiRDC1LrBKRwY3JlSIQfLKU70m9qb0f0Tc3RRr7hqMvfwXhz7wEEfoYJUkyHZXB+gZtGamrOqJxNKM7tboQ8KG2lxHOrp43Z72fgIicLzFUQQ4tEhG1mTaKyoVln6GrmhzdpqmcYBgILroTGQ52uaGiVT+pygl92d+pELqhYUiUsgouksKubhnMXSaTnjH5HTSuppRK+SoTeNVlFlWxdZlDaDYehE7TnglqnZ/Y8n6qnalBKIMCGQGRduIB5GWo0lHjwjiKBgSguY4jSf1R3CwXKRomWtFPklJJnJOAwWiRzRI3i1KaKzjdExL7sSETjdJUl4ciLP/yx3+7nqFVHp+puc2iaF0yGVMHtZNRqnGs0mX+jCm5reNQfHnQ3gbjDDTRccjLKg9O9pAx144aBYEUnoh4+6B8K6HMs6YaOqciHJ49sSl54DkSUZnaU6XoHes9QRx89WmeTdVnk9oJzRWiRDWQx8oOL1IaSaruEsL8MHcRsPwhmVBwniLMG3rhSvsaSiCykBJ9jR5CFVEfmc8ylMcK7ZNl8+0uPwzKfOHqIu1jmlJIHKKFeeE+RM1JXOvloQGt1zn7JsvBaHdMGlmG4CLaYHJ7kGKX4d5OE5GzQ5OEir0cT3hhofXYGbGQzOJSyCYforgBr/y+uqrNipE/7O65pDUb7wfhpSZHOoq6ASKpasqvcTwA==</binary> </binaryDataArray> <binaryDataArray encodedLength="592"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="43" id="controllerType=0 controllerNumber=1 scan=44" defaultArrayLength="15"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.1496457021462" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1646.432373046875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11600.921875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="462.09176251452823" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1495236329022" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.44.44. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=44""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.8199" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1027.27@cid35.00 [270.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="270.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1027.2607056595309" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1027.2607056595309" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2317.82177734375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVEU6QAAAAAMN1V7l/7/f5/VFz0Ac06pIEOQBf2fDENGGSQbqxz9an4e/pzdBajEohCtDXNBCUhyL9AVHh/OGRDrIg/aYFfg</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XcFe8VXxXSJec1/BWSJaAl5zXgVUE1/BX2JYlV5m</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="44" id="controllerType=0 controllerNumber=1 scan=45" defaultArrayLength="10"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.0770145022077" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2158.673583984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9406.8212890625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="467.02990811020527" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.8856011717724" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.45.45. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=45""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.862603333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1429.30@cid35.00 [380.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="380.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=43"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1429.2874406245221" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1429.2874406245221" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1872.902954101563" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="68"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUg8lwAAAAANgm5YF8kkXB8vvlWdYcWoFglEZxf5woINL1tAYLDGinED3ItQiUvfU8A=</binary> </binaryDataArray> <binaryDataArray encodedLength="28"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WMFdslUCVRJaclrhWQVZGF9oXCI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="45" id="controllerType=0 controllerNumber=1 scan=46" defaultArrayLength="26"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.31229989493062" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2935.544189453125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="20337.80078125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.31228463625322" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.266465968265" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.46.46. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=46""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.906233333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 741.20@cid35.00 [190.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="190.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="741.19392788925313" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="741.19392788925313" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1801.882934570313" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="160"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QV/AfwAAAACOLmVhUImIYw3XDQsQcLRC3p3pmIkvnY2KhW9XlmS+PBPzeLwbsy0UkjDmxRJjIsIDAnAfEBAJop0IY1QyENOBU84EUNXCWfAtG7AD96rOCHkd89BXU9qkC5x9S7DXvjf3F363CgCtQKaAXcWxXg==</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WHtaYlgCWPFT0VnBUPFQ0VrBUqJS8VixV7Nd0VUSVHJcoloSXlJV8lDRX/NaI1GiWflWVA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="46" id="controllerType=0 controllerNumber=1 scan=47" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.3079206545047" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3119.734619140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="16777.1640625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="185.13589849842995" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.362656532217" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.47.47. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=47""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.949783333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 698.11@cid35.00 [180.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="180.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="698.10447855842551" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="698.10447855842551" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1764.214965820313" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="132"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVy+bYAAAACFFCZTl5YqWJhXhgsfZNnREPfLRwHi7QgQ5/+djgoUW34ZllRMoECRY14HLoXtQOn1LAOVHUwKDQBrkICYa/4jkNPKng4yN7zAvVrFQgcfsXwRjI9PoMKTeds=</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UyJQPFuCUnJVU1IzWMFWIlITVyJf8VdzUtFX4VkCWyJY8VrxXzJRF1rj</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="47" id="controllerType=0 controllerNumber=1 scan=48" defaultArrayLength="15"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2612788076337" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1231.889404296875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7810.45703125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="486.61632753079067" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1990.4077417795809" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.48.48. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=48""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="1.993383333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1533.49@cid35.00 [410.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="410.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=43"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1533.4765720249791" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1533.4765720249791" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1655.808959960938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUsuhQAAAABwIlZnk/7/fwFntezhbQR4ceLvIHG3JNUR3W7L4MN9kg4SuM1mFfu2aQHV+msg24G7XQS4FkkgyTdNXBadPGY=</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WaFWkV+BVOFRElqBUoFUQVhRVVJc8VxxUNRVBFZx</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="48" id="controllerType=0 controllerNumber=1 scan=49" defaultArrayLength="206"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11958293493552" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="60273.5078125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="6.6545e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="401.34124134800669" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1691.2630223901815" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.49.49. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=49""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.036533333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="164.383193969727" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1040"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="572"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="49" id="controllerType=0 controllerNumber=1 scan=50" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="221.08401504677519" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2338.1416015625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="14912.033203125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="157.44121583712467" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="479.60122547268429" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.50.50.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=50""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.066671666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 533.19@cid35.00 [135.00-545.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="533.18967016150066" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="135.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="545.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=49"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="533.18618874597621" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="533.18967016150111" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="6601.4267578125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="124"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWdGdyAAAAA24INyjf//fxrg2zGVqTlRMfoxEvYZ/ZZl29UMf9dsEChBDf2uk1PgzDA2UZY7PTqaDunJn9vdWKQz2iGksW1xR5b2iXa2HSCgRyYBk2ulrgc+N7EQ</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WqFQ4VMCWTRbslvhUile8VOhXKFbA1PBXgJZ0VEyWsFZ51UiWsFc8VLi</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="50" id="controllerType=0 controllerNumber=1 scan=51" defaultArrayLength="21"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.21487323946369" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="868.727111816406" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11388.970703125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="193.90498413094369" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1796.7107074299543" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.51.51. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=51""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.113176666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 607.21@cid35.00 [155.00-1835.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="155.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1835.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=49"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="607.20536577246355" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="607.20536577246355" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="4862.2353515625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVJos0AAAAA6YMY3xndwOByx5WyT6B8lF/OMhpEqX5ccOeXRB1ghRSDOj1t+lOVw0hsVhvQdR56pkbkSkQkaSKAhjVg0sA1tPh4AyYb0QEUqJNIEO+lwgSlVYlClIk4x</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XNFVY1zRXiJasVnhVDJWwVVjXgNd4VuxUfFXAlfxVbFX4VQyXvFU0Vrh</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="51" id="controllerType=0 controllerNumber=1 scan=52" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.3088209164741" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1346.169799804688" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7417.224609375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.21145529571669" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="553.03568027693893" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.52.52.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=52""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.159511666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 667.18@cid35.00 [170.00-680.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="667.17707754074729" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="170.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="680.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=49"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="667.17476554864777" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="667.17707754074752" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3593.71875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTddgAAAACXvu9/1///fxqOLrIHfkp2Eh3qU57zGVgM7l8rEIOyVV0Yb8h0ABMeQxBrZepj</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UbJSRV/hVOFc0V1iUhJdQlbxXERaQg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="52" id="controllerType=0 controllerNumber=1 scan=53" defaultArrayLength="33"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.30593702643736" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2308.844482421875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="20916.193359375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="102.26489216895826" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1259.5862790563392" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.53.53. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=53""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.205843333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 416.38@cid35.00 [100.00-1260.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="100.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1260.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=49"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="416.37695411241799" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="416.37695411241799" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="5194.3232421875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="196"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWWsBWAAAAAnPkJFrcT9SZOXpJwRqxQqn9Wp1BEC+iUUnNKknu99RghmDNUZe0SUGVa0KIEgv1+BeYgkMWL2Z1mYgVAwQO05kQ1WB//pIwlUYeyzMIkNLqRh4TlS+Y/bzWm3Vnxw8+TQ0QLOqC3h+M7bcDTTK4cOOnCigE1eM0INf/8fMN2oRuqdpCj4BacmD3A=</binary> </binaryDataArray> <binaryDataArray encodedLength="88"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UdFXU1+BU7FYwV7RVsFd0V8CWjJVCVXRWuFSwVgjWdFZdFfxUSJewVPBUPNS8l3hWrFawlOSXwJdclPRWdNW8Vvx</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="53" id="controllerType=0 controllerNumber=1 scan=54" defaultArrayLength="15"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.1761965448495" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1655.199096679688" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="8412.703125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="421.13540807282789" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.2465686815597" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.54.54. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=54""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.25101" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1512.11@cid35.00 [405.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="405.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=49"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1512.0967592385284" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1512.0967592385284" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2630.497314453125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVDlgwAAAACS6C5vIP7/fwcPKK/gtUzVUwu6wurCJijoEFpX0QJmAcA5KLK1idBCorCdjsqNCo/K8RDF/N+iBEONOyCnMHTZ</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V5FQ0VOxWPFRUVICW2FTgV9hW/JSQVqBXsFXdl4E</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="54" id="controllerType=0 controllerNumber=1 scan=55" defaultArrayLength="239"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11952190017854" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="43581.0625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5.519435625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="400.34439195072292" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1690.8738656416049" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.55.55. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=55""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.293376666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="201.184127807617" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1184"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="656"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="55" id="controllerType=0 controllerNumber=1 scan=56" defaultArrayLength="22"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.2974715561379" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1862.340209960938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="14674.306640625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="230.29059747890409" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.297593625382" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.56.56. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=56""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.321231666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 845.14@cid35.00 [220.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="220.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=55"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="845.13282534248151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="845.13282534248151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3030.696533203125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="136"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWHHAIAAAACsp+9/bv//fxBfTrEXM68CEdywVBBU+IUXfODWCMWmrTCdHIf6EOybt5bz2ZcOZRNQcGbvBDwAiwBSQODrVQMKXGOk0GBmE7uVCfuQBumRCdBU2pe3BMc9XYlPWqqA</binary> </binaryDataArray> <binaryDataArray encodedLength="60"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V+FasVnxVpFewVECVOFdoV6hUhJUA1oSWqJYc14SWRNYAloSVkJetlAiVkc=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="56" id="controllerType=0 controllerNumber=1 scan=57" defaultArrayLength="12"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2025635014656" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1752.204711914063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9289.47265625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="478.40903170140393" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1918.2025635014656" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.57.57. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=57""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.363968333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1382.19@cid35.00 [370.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="370.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=55"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1382.1778262951391" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1382.1778262951391" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2058.619140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="80"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVDVi0AAAAD8ctZ9G/7/fwNc7KERXdlPwCJIgw4t3/Xw+toZkRQi4ncF4auYIfdlZDAOz2QtAzL8lSA=</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WmJQQlhiUwJfo1qCUPFc4VBkUZNWUljW</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="57" id="controllerType=0 controllerNumber=1 scan=58" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.1340826558092" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2773.015380859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11257.2783203125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="658.39712453166544" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1733271354035" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.58.58. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=58""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.407468333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1690.89@cid35.00 [455.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="455.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=55"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1690.8751937549753" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1690.8751937549753" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1945.761352539063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUe56IAAAABkhwp6pf//fwVCcMkQ7qr8HgOVmFUQ+07jrgTl/Wggh7MuQQp7HBjQm7WkUQETohjQ</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XiJbYlHRWEJX0VlkXoVW8VrxVdpcNg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="58" id="controllerType=0 controllerNumber=1 scan=59" defaultArrayLength="19"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.30358719011093" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2479.693359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="14513.9921875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="184.77454249924935" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1609.1013883275889" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.59.59. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=59""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.450945" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 626.78@cid35.00 [160.00-1895.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="160.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1895.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=55"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="626.77514412385051" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="626.77514412385051" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1916.76611328125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="120"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QV1B1AAAAABD5ndU5BOkVBfq0eSfi/z6EDz25wlGIEEQW+gjjhuv5YMFe5AhMA4LP94G/zjz4F+57hUHncUHoLdnc6EH2Zx0WYw3DWBraNTpB5NZj3DLP0E6</binary> </binaryDataArray> <binaryDataArray encodedLength="52"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>W8Fecl0TULlb8V4CXLFf0VVCUONS4VNCU0JcwVcTXpVQUlykUPE=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="59" id="controllerType=0 controllerNumber=1 scan=60" defaultArrayLength="17"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="196.30171037278626" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1607.433471679688" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="8264.3681640625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.30171037278626" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1310.9534480776513" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.60.60. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=60""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.494753333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 514.27@cid35.00 [130.00-1555.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="130.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1555.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=55"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="514.26634968384531" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="514.26634968384531" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1899.589599609375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="108"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVqK9IAAAAA3lWlRzP7/fwpMDoHRGz/kcTvu2kFzOzcRh/m6WWiOXqnqP2BgakNlNQAeCSqguvId5A/bPVCwYQuSwgtlt0DgoPLjJAbGrdTQ</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V0ZUQVphU0FZQVCxWWFdUVqhVOFZUVNBUGFS8VVxXINU0Q==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="60" id="controllerType=0 controllerNumber=1 scan=61" defaultArrayLength="266"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11958293493552" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="36133.1796875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5.2051896875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="411.36161482414894" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1698.9646151069958" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.61.61. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=61""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.537961666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="222.097991943359" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1320"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="724"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="61" id="controllerType=0 controllerNumber=1 scan=62" defaultArrayLength="11"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="479.57244753963829" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="861.514465332031" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="6328.634765625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="479.57244753963829" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1918.3165761749822" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.62.62. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=62""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.566545" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1536.96@cid35.00 [410.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="410.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=61"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1536.9465416399923" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1536.9465416399923" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="2267.91943359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUPcAQAAAABlCGhKiB05S6KtcDEg6cypeHSOcSsGROmdAgcARLyL9wQ8UHegkkqAbpJUmoc=</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XlNVElxCV8FXElYCWVJb8l+xXuFVEg==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="62" id="controllerType=0 controllerNumber=1 scan=63" defaultArrayLength="13"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2349118510176" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2866.603271484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11251.93359375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="484.81872894719106" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.5085292783119" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.63.63. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=63""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.609128333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1683.82@cid35.00 [450.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=61"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1683.8052556632911" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1683.8052556632911" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1919.398681640625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="84"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QU3nWgAAAAChw0Nx8P7/f5/LwZQbXaUHGY9vWZSE004JDPOIUKTZD3kDmHhkKcYLD1DswEpzDVEIg7luqHDQ</binary> </binaryDataArray> <binaryDataArray encodedLength="36"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XAJYIloyXNFUwlrRVFVaUlHRXmNbQlM7XEI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="63" id="controllerType=0 controllerNumber=1 scan=64" defaultArrayLength="12"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.1965202916863" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1675.357299804688" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9337.1787109375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="461.9935881017995" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1966423609294" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.64.64. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=64""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.652538333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1611.87@cid35.00 [430.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="430.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=61"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1611.8558856920506" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1611.8558856920506" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1678.748413085938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="80"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVEVLcAAAAAZclB7Jv//f5XkRrwV6emGr8do2Q12AtATFc4WDEQEB6G0NbNw9iNqERlnHNYIJYvjYA==</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VDJSwlMyWcFXE19iXwJTVF/BXCVXEluG</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="64" id="controllerType=0 controllerNumber=1 scan=65" defaultArrayLength="14"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1939.2648790680987" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1851.565673828125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="11688.8291015625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="484.84988724100498" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.2648790680987" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.65.65. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=65""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.69607" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1628.33@cid35.00 [435.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="435.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=61"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1628.3157415603844" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1628.3157415603844" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1652.951538085938" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="92"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVAsUAAAAAAyGIZ6Nf//fxIOe+MIZQm7ELipFD6Z9og5HYbA9ZCPfN4CPUC/IQdUqCCA6i2tBtwt1CAJKpiyDFyGcaA=</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>W5Jd0V9iW5JS4VPxVvFYclOjXGVf8VdDVFZcNw==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="65" id="controllerType=0 controllerNumber=1 scan=66" defaultArrayLength="13"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.3088858126355" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1646.786743164063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="7554.25390625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="435.17851823506112" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.1806512900191" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.66.66. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=66""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.739411666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1586.14@cid35.00 [425.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="425.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=61"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1586.1261109962898" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1586.1261109962898" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1651.991821289063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="84"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVEUxwAAAAAPayV0bv7/f6fYkyl7i/+Rpy4uIEOfSSUIq2/Z4NvSeLwIcrEgQDHMGsyRzLeMBvaaihBjTv0d</binary> </binaryDataArray> <binaryDataArray encodedLength="36"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WUFeMlBhWEFTgVdhVWFWgl9iU3FSgV9mWqQ=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="66" id="controllerType=0 controllerNumber=1 scan=67" defaultArrayLength="257"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11967448707202" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="64921.46484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="6.27186875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="409.27044359808127" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1697.4356978309852" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.67.67. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=67""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.782545" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="226.027053833008" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1276"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="704"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="67" id="controllerType=0 controllerNumber=1 scan=68" defaultArrayLength="22"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="520.13808460741097" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="7832.4619140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="37053.3046875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="152.6331913164822" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="543.70428527467584" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.68.68.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=68""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.813838333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 539.16@cid35.00 [135.00-550.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="536.16474233879387" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="135.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="550.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=67"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="539.15613648386011" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="539.15613648386011" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="8982.1708984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTds0AAAAD8xYZjWv//fwpP5pPhddL+EchZDqCYLzexAvoTWNwj6RGRCsWXxO+NH4D7zQhetj7hMUw4wQmXTPApPQYyDdwZu8nJFRRc+WwcvZCInADPd0UsoeRRhtA=</binary> </binaryDataArray> <binaryDataArray encodedLength="64"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UmJTRVQiXPFZsV07URlbVl/BXdNdsVKhXOFRclyCQGIVYsUUNInhRdAVWEWuIA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="68" id="controllerType=0 controllerNumber=1 scan=69" defaultArrayLength="15"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2623774308267" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1715.421630859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="10959.9697265625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="436.00120508802263" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.0854372800161" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.69.69. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=69""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.860176666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1439.54@cid35.00 [385.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="385.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=67"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1439.527361867214" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1439.527361867214" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1772.917602539063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVJiJoAAAAD3vDx9cf7/fxkdZAkeLJyUBKf+42CnrQBZlHFr2wdJ8Dsx6lK10AiNJmsvzV4Rg7JkIAL5EjYMXEq3kQ2UyUA=</binary> </binaryDataArray> <binaryDataArray encodedLength="40"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WMFRAloiXJJaEl7BUgNehlrhWzJQA18CWCJTtlqy</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="69" id="controllerType=0 controllerNumber=1 scan=70" defaultArrayLength="9"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.1783937912342" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1328.281005859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="6875.38720703125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="484.83536094535725" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1939.2125113625966" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.70.70. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=70""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.902885" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1693.70@cid35.00 [455.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="455.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=67"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1693.6851691492654" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1693.6851691492654" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1704.254150390625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="64"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QU2S8gAAAAACDAVw++VucALekwEQPZblRANsyGmwNz384gZ+BMPQro3bJwRYtVCA</binary> </binaryDataArray> <binaryDataArray encodedLength="24"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>X2JaI1ayWEJa41QSWgJQNVwD</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="70" id="controllerType=0 controllerNumber=1 scan=71" defaultArrayLength="12"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="355.06963769613509" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2007.22802734375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9651.48046875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="184.20437149927568" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="570.05722931153662" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.71.71.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=71""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.949678333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 613.18@cid35.00 [155.00-625.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="610.18368199173949" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="155.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="625.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=67"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="613.17529042225294" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="613.17529042225294" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3332.583984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWY206AAAAClkt9/vv//fxp/9CgH8sH1YKPKpynSgxIX+m0GpN5CIFOsaj4Cov9e4T5pwhD3KPhz</binary> </binaryDataArray> <binaryDataArray encodedLength="32"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VuFY8VRzV9dahlo0UgJYwVTxVhJbIlbB</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="71" id="controllerType=0 controllerNumber=1 scan=72" defaultArrayLength="17"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="1918.2936271571866" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1547.454711914063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="9424.0546875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="479.5891710892754" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1942.30806531089" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.72.72. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=72""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="2.994845" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 1615.70@cid35.00 [430.00-2000.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="430.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="2000.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=67"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="1615.685852154731" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="1615.685852154731" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1648.824340820313" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="108"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVDVlkAAAADdPCZ+J///fxHEWZeWXTUnGK2jORxshSqWYezpBv7GuRC7X1G+HnywRA75HwzgZE5QUwbv75/pGs8l0N41w1QF+ClLmdz15bA=</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WKFYIlxxV6FT0VpBUmJYYVGBUOFRYVNDU5FXQVsGW7RSUQ==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="72" id="controllerType=0 controllerNumber=1 scan=73" defaultArrayLength="201"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11952190017854" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="53198.93359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5.2109640625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="411.36164534150367" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1696.9315518549431" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.73.73. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=73""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.037086666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="189.870208740234" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1008"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="548"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="73" id="controllerType=0 controllerNumber=1 scan=74" defaultArrayLength="34"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="429.08829179029334" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.66624203125e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.515229375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="116.36697711950515" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="430.08898637429178" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.74.74.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=74""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.067838333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 445.12@cid35.00 [110.00-460.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="445.11955241755703" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="460.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=73"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="445.11674970150455" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="445.11955241755703" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="53198.93359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="196"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXFyCoAAAAAVO+F+0v//fyBBonrnC0keWNrmC8a/RSDrWjQumidNJReph5Sd8HdLpUAT6TDESeG2mye5fkXHIBhxTwEPuFf94lRJxwZP8yMgbHyHbpueCVuZ1RXtHdG6dxxDAgQMGwIQEELoQh4nltzxL1kD2UFeYWnSGEzBw7TlIOmAOmKWT3bBA6f1Buo7CDM=</binary> </binaryDataArray> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>X6Fd0VgiXMFfkVUSUEJd0VoaVIJYUlzBS/EV2CVqFbkVeSWKFddlPBULFfcljhTPVFyRX9xWZFY/VLJewVXRUUMw6oJEj4A=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="74" id="controllerType=0 controllerNumber=1 scan=75" defaultArrayLength="22"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="519.13790998813067" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="13479.96484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="58954.16796875"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="139.65879892228503" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="520.13973254264329" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.75.75.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=75""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.110895" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 536.17@cid35.00 [135.00-550.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="536.16462026952775" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="135.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="550.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=73"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="536.16616322505149" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="536.16462026952775" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="16885.662109375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="132"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWfJGWAAAAAo4s5nvv//fwc7yIzhLIImiRPqXySUXxJO7AMS+/1ml7i/HJdpA+0BHl5QIIw7Qh6ZFOqrE/MhipzJ1SYEauM2IKQRb+4H82xOEGz6rP4BiOcc0aVs1qmjGSlQ</binary> </binaryDataArray> <binaryDataArray encodedLength="64"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WpFQ0VXhVKJQolgUUEJQ4Vo0WNFUAkO2JfyFACW7lZslfBUMFLKyTuUUikNNJBA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="75" id="controllerType=0 controllerNumber=1 scan=76" defaultArrayLength="19"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="281.05113618875168" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="17665.412109375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="58259.49609375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="141.04639253150231" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="504.10731435017084" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.76.76.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=76""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.154501666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 519.14@cid35.00 [130.00-530.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="519.13815412668487" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="130.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="530.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=73"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="519.1363084392151" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="519.13815412668487" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="13342.1845703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="116"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWjsNWAAAAAjC9pte///f5wTnhMSFSyXnqrr2RE1xJeUhHumB+2XuSBY4DEtHzvfwhMI0BabPtKrD9UIlBlwYvgpqJtFQJf2UtISG4TZB+NFFdlXYx8w</binary> </binaryDataArray> <binaryDataArray encodedLength="56"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VbFXwVrhWtFYfF4iX2VBBUVlxT8UNQFUElvhUSJekVgkUjRD3zSLQQ==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="76" id="controllerType=0 controllerNumber=1 scan=77" defaultArrayLength="26"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="999.18763888293995" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1051.48876953125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="13204.1337890625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="142.59633846870315" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1075.3305659588898" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.77.77. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=77""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.201686666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 479.57@cid35.00 [120.00-1450.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="120.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=73"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="479.5665503521717" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="479.5665503521717" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3274.93017578125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="156"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWvryoAAAACehmt8z///fyW0v3nNc73Rbi0aiUO4M7H9aFIZr2Pts82Jca5WElnOVReKmwN8FBnomhoOLDIKVMLXUB13dEoJA5OPIAwIxuMFK1RvgSF9z4AGkYfEGzE8pgiHnViwoRiBYQP+4+Uw479ovQ==</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UaFT0VahVLFQkVWhUPFcUlMSWtFbwlZiU8FXkV7hW9FY4VnRXaFUsVPRW2JY4VKxWxRQ8Q==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="77" id="controllerType=0 controllerNumber=1 scan=78" defaultArrayLength="29"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="365.1049646761702" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1652.524291992188" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="13951.728515625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="140.8380658083874" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1411.0210311852338" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.78.78. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=78""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.244646666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 486.63@cid35.00 [120.00-1470.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="120.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1470.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=73"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="486.62651546906574" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="486.62651546906574" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="3178.145263671875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="176"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWHPBqAAAAAYI2FOZVrgVJLDS/0eEog/Cb28fOrCz90UgqlCGeTv+QGHGwEZdoyVSTbe26nP0tBhZgp0uc/Ql1CgdclhEh5r3gXgR03Q9onZowJtK+LAuawbQhuJxFGfSfTSC49aduB7Qm4xAOAHruBWY34Ro8VmANi9JvcIawyC0A==</binary> </binaryDataArray> <binaryDataArray encodedLength="80"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XjFbgVUxUHFRNlRRWtFVIVhRUkFaEVfxXMFVdldRVLFTsVVxW1FVAlhRXUFfoV5BXJFecV9BWCNc0Q==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="78" id="controllerType=0 controllerNumber=1 scan=79" defaultArrayLength="212"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11985759134302" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="44253.14453125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="5.633291875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="401.34227893807252" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1694.0265479959" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.79.79. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=79""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.28806" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="201.708236694336" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1064"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="588"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WrVeB1HnTaA1tfSwk06zFY3FR2UHdJkBXideFVkGTQEk2IFTGVkoQMMkkxJGwBVtpYyFFoXOtXtVn2ScQltYWbRdN1+3VIhN3KQr0kInFYlkYJNZLlwnXMVCbhUpVeF0EBFdxVpNXdRc5k8RFHCRU5pEkxX5ZQi182Ts0khBFRS0UAJZB1AWSSckNxFdyFHaVsRfxVBkXCdH8hXCZRRVuEUlxSrE5DFWCF6mVpRXWlWXXohbZFCqVlRZl1rcWCRQtFoGWwVY1lNmXHRaKFV1VtZY9VAuWYRUy1mUV1RYRFGEW8RTtFu0UvhVFUmAFbZV+mUiVYBVVkWTVVpFkVXLRYJVuEXpRapVqFV4VZBVXESn0VNlV+RRFVSGUaRfhFVXUNRdZVNVVaRdtFHVXFZWtVfkUgVXBVpVXMVepF7UVrVahVYlWvZdVlglULVSdVC1X1VWdVFoUBhYCFCFW5VdNl+mVUdfN1XnVTZcGFGVXgZW1VHVVDVBUBUPRfaVrHVRVadVhWVhZchVfoWJVUKl7XWzdbhVr1UhZblVk1VwdYSFamVHZYl1rFVUdSNlWVVIVVpV5WUtcA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="79" id="controllerType=0 controllerNumber=1 scan=80" defaultArrayLength="31"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="301.14058883943034" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3242.130859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="24908.158203125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="101.98195814249091" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="396.36819423082926" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.80.80.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=80""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.319006666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 413.27@cid35.00 [100.00-425.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="413.26614190774541" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="100.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="425.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=79"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="413.26697686257501" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="413.26614190774592" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="14602.98828125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="180"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXPoFZAAAABgyuF+vP//fxQr0ZySyUW2Ha+YGJjdE1QVrtnoEA+zLAsCGZ7hv47PueWxtaqy7NOWW2Q8lWNszpmscRsQP2k1GJ6jtZDQo1UJdOAdMKdRjywJV8S8GSd4CBmQMkeQa1bggZkO1EaYwz/BmAm9uB34N9ENy6R9INa2JC2Sfi2+</binary> </binaryDataArray> <binaryDataArray encodedLength="84"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XdFUElGhXAJZElUSU9FTsVPBWZFaIlXxXfFZElvJVBJdsVbBVrFb4VhSXLFarFumUYJUwV6CUMFeVFK7W1M=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="80" id="controllerType=0 controllerNumber=1 scan=81" defaultArrayLength="16"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="445.11973552182894" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="23394.8984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="43146.23828125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="115.18699307556196" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="446.1200646773317" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.81.81.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=81""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.361988333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 462.15@cid35.00 [115.00-475.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="462.14590034736165" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="115.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="475.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=79"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="462.14663886796745" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="462.14590034736125" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="14598.16796875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="104"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW/7K4AAAADhex5zrv//fwSeyyggUG1tDRojt1ML+jTKIH0RnC0CIVziUGzT7KqZm+/uCEPAnDABm5LMnpHx1BDSewyUE37krib1AA==</binary> </binaryDataArray> <binaryDataArray encodedLength="44"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XbFQIlwSW7FY8lmxXdFd1FjhWLFTJF3cXkNW9ENrVDLR</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="81" id="controllerType=0 controllerNumber=1 scan=82" defaultArrayLength="26"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="304.89553573641473" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="13287.9921875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="40370.11328125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="115.5692000574671" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="394.90586361950034" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.82.82.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=82""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.405751666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 439.38@cid35.00 [110.00-450.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="439.37795182587604" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="450.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=79"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="439.37678728273085" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="439.37795182587581" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="9416.62109375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="152"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW23MAAAAACYpFFrt///fwtVJqYQvIR4/ZUXqjUcHznjlaBHjAkAsBcwQSyLzZeUNLiZ+1G2nggYDp+bo24Y0N+hEbp6wwxHp2QgNA9bvSrwullNSyChdZ1qEgGhYpEKgD4YU13CGaoccSmTb2FStwgw</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>ULFUoVvCVxJQiVzyXKFUxVo3WFNeMl7BXchI4zWpha8VHhV0JcHVGSWwpT8VgiWNFTQlKVA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="82" id="controllerType=0 controllerNumber=1 scan=83" defaultArrayLength="57"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="341.01764698363104" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="67324.703125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.06111296875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="109.25257298615395" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1223.5329799750582" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.83.83. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=83""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.453015" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 429.09@cid35.00 [105.00-1300.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="105.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1300.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=79"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="429.08686113669586" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="429.08686113669586" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="9151.994140625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="320"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW5XOsAAAAB1bpZnMyCKcJewLwsH8aVxQGigO+sWY8zBlXL3nhcrxmUYccLJAod5LuGsR+e5KGjWSlA2QhqkcuEarnHEl73GKhSLEOWRiAYenYJuLJlVbT4cGsWhHK5GApen1i0VLnPhm7A+PRZTs6UV2zTBk4ifThEKNJWRjK0slPR0abIRHhRMKIaeZ56oGf88ARjANgWYJKLZPEr3Kxd+uj6h1BboXVimsCQJVW8XwAtMTIEAwIjE4OK8tUSc75lwDqg6FjCXveErFZA0xg0b8Ssg+X0nGwtW0c5wBzxH2A+QdwAQuwgcJAVweeIQ</binary> </binaryDataArray> <binaryDataArray encodedLength="160"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UQJT0VHiXFNaYl7xXgJY4V9TWdFWoUIENcs1DUU6VQAk2wFbdlLSWeFYlUSYRVc1RSQecVQjVbRHnBVjI99gFHPjXzJZslADUnJPriXTNEtkWrJcn1piVyZUvVvhX/Ffo1rBUjJeolXxWKdS8V/xUPFSs1QSVNQ=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="83" id="controllerType=0 controllerNumber=1 scan=84" defaultArrayLength="42"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="434.85302012786929" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="43910.52734375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.28804296875e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="150.42301766504502" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1223.510153019208" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.84.84. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=84""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.498343333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 503.11@cid35.00 [125.00-1520.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="125.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1520.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=79"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="503.10641932066449" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="503.10641932066449" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="5011.89501953125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="236"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWOxOwAAAADNaJFcx+3rdQt7tInpOPAD0fwwwPkKUpup+6xscdoNUvlnScCJnhSgwUleIxkS+3KhYKEDKTROHeo4HKYQIJFnlThjOR4NEjuQvgn1HgOjURFJGjGZ9yfOnVfvfRtywoIDRUY2EHdv9o4SI8JGlCRMZyiZlYNiaEqRpZew9PkqMkt6xW45EK9pLJzI3EQhMdYQmMDiEQ05OHoQFXCcsQc5T85w/wliPA==</binary> </binaryDataArray> <binaryDataArray encodedLength="116"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V2FfUVXEXsFaIl8SWlFfIUFrFOsBVDFZxVDLRw8lyxXXRUt1+hUHJUUlHBVGRYOly2XkZaCU7cVUM14YR4ul5zUzdWLF8CXiNe4VmxUuFXcV2BWUJYow</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="84" id="controllerType=0 controllerNumber=1 scan=85" defaultArrayLength="560"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="424.89664154491851" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.53614890625e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="4.8563585e06"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="400.93584880572797" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1593.5712508806228" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.85.85. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=85""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.540868333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="109.449501037598" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="2560"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="1676"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="85" id="controllerType=0 controllerNumber=1 scan=86" defaultArrayLength="46"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="424.89642792343528" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.106067421875e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.7722553125e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="127.89638038928665" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="486.62508603272289" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.86.86.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=86""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.568841666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 492.89@cid35.00 [125.00-505.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="125.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="505.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=85"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="492.88647933730027" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="492.88647933730027" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1.0701325e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="252"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWshQUAAAACvh25su///f5l4enGacK2sHZ+/ZRURDmwMU8zv6bZivdH64YQhWKhKeVJ8aqo9FHIZ4zF4Ha6sOg7c0FvpigbOwdKyhqlszuN6N1zSHqy+oRlDB/WckCkpqiARMJGoeIENzVkP6nd2Z5I2gLmRiR+OIbSHkcfsY1BArUOyCLwa7stJk+L13Ps0vhUw05geMTQVG382NJN0zAYvdMWKiFdlGUytgZMFE34LfEOTGeUoOFmJag6g</binary> </binaryDataArray> <binaryDataArray encodedLength="132"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VaFUslnRW2NcAlsyVCJfm19SVwJTdlA5VoRbElrRXZFZlzMhQV5dX4JYFFCCVzJXsVvxUvFHi1X+JVI1RkT6AUTwFYJVFzPwCxQuMVeDVrFd0VfOV3Ve00reFX4VeiWzMA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="86" id="controllerType=0 controllerNumber=1 scan=87" defaultArrayLength="35"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="486.86641785627268" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="52713.265625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.03230859375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="142.41518745011206" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="562.03944097609133" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.87.87.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=87""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.611766666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 554.86@cid35.00 [140.00-565.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="554.85426677240787" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="140.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="565.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=85"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="554.85599038907696" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="554.85426677240832" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="71749.7265625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="196"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWnEc0AAAACHVa1yy///fxMoTrsAZ+vr4CUE5sEGR8WA4BK1tFIEpcwE6VV3tGqbUNMP11DRIF2tP+0Xy2SFGVsUkwL207gQmNg7zRlbSWEQkKrJH8MfYRrxY5iW8bGCnqIhSCZEXrtT+5PcgptEtYGFsvBB+80+SSq/QXoRmbQsCciTKDvBMmKCsXBA7SI96wg=</binary> </binaryDataArray> <binaryDataArray encodedLength="96"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>V8FUwVPhX8pQ4V0iW3pSpFaVVmJWMlHSVgJZMlRmUxJFaRU6NX4VfRVhhbelVSSe3EaBFW1lhlVfRUHVb2VKJLwhUrFdoVfy</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="87" id="controllerType=0 controllerNumber=1 scan=88" defaultArrayLength="32"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="440.86979385410552" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="4130.06689453125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="30868.447265625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="145.15962843350198" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="532.00034927925162" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.88.88.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=88""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.65547" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 576.85@cid35.00 [145.00-590.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="576.84517201410097" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="145.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="590.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=85"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="576.84574573758971" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="576.84517201410074" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="61315.484375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="188"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWtbU+AAAACAwxh8v///fxGl0KqZbLS+mYzbzg0nrh8QESS27ZRRxPcD1GIwEAIdt+4Uggr1GxYTBpGE1BYQkudFGEKuhJPUbUsDEU0AUFt2Q6od/MlbEByzB5+Vt3CU/UcND6wooBDAWpnuqwq1Qlq8LB4J2CUSyK1En10shqqYgFEzwmYZcXGY4A==</binary> </binaryDataArray> <binaryDataArray encodedLength="88"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XyJTAlsyVfFZe1LhWwJfwVpCX4FSAlDBVWpb4V3RWQJdBUIgFQA1/SWyJcE1YiXTNUol9XWANeQlW1XsdaYlwiA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="88" id="controllerType=0 controllerNumber=1 scan=89" defaultArrayLength="28"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="598.06909063019111" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1817.327758789063" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="17947.91015625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="191.63156326150965" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="603.27550637304955" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.89.89.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=89""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.69927" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 644.84@cid35.00 [165.00-655.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="644.83273105161584" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="165.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="655.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=85"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="644.8349624771256" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="644.83273105161629" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="49787.3671875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="164"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWVUwgAAAABzrL1/3///fy3fuxHTIrApEOF60Y8FUEJab34AYMEwEF5Kes4f87LvmkliMhHdt4UDtQxfEX1eHSB0NrGdF6WfEhmV9M6d6FBSGh5P6Q9HF8/pndZ34uUMEhdd5Bga6MAZHBP0cpqxr5mVy2wULnjHQA==</binary> </binaryDataArray> <binaryDataArray encodedLength="76"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>U6FewVnhWmJVRVPxU6FeQl3BXNFc8VzxXsJRQlECUxJT8VtzX9FT8lJCWMFV8V0CWzVZF1zhUOE=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="89" id="controllerType=0 controllerNumber=1 scan=90" defaultArrayLength="33"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="453.90123342171825" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1953.930297851563" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="20826.9765625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="136.1529804518953" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1369.8393684629823" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.90.90. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=90""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.746345" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 498.90@cid35.00 [125.00-1510.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="125.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1510.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=85"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="498.89644397986842" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="498.89644397986842" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="45589.84375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="196"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWus+QAAAAAmAcF1yvsbdgKw1vQRxzbOgNeCfR5JbTGm3egwINWV5wlC2ZeJPy6BgNdGhcECuv2D4E1WGZENZETk4ddW0hFS9msp2XnM0XcUSomT12ZqwIYmIJq1kU0+YhGPYEKZaRMz4A5kxoEHllnTQPN7E7MAqAEPkFDVoqENGKUPMPEzoQkZjK37CBeslBA=</binary> </binaryDataArray> <binaryDataArray encodedLength="88"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XYFZUV9RWcFYJFuCVZFYM1qhXDJSUVZBVpVYUl1BWpFfclwWXdJRg1KnXVVcQVphV1FWcVKRUZFbMlxBW2NfgVxR</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="90" id="controllerType=0 controllerNumber=1 scan=91" defaultArrayLength="317"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="427.07558068363193" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="2.32096953125e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.73892575e06"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="401.00201043111633" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1686.5241722846306" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.91.91. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=91""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.788888333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="75.766189575195" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1516"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="972"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>SzNEtlE3LsFNaTRwRElhNSqlCfQX9UEAJBdxTkk0bnJC7aW6td6kE2JC4hUj9AeRWKxey1+uXtheHEr2FDhXV4xXiE3UFR70XzFOA1SoAVMMSyklWZMaqDRdh0qgJHNRVX1QTkf2FPzxP5NBT0M1p/VnpKziUE5TCVJbWxxD5jRH9FjZRmYk2VJFqhRVsV1bXV9bvkEiFAKnUE1Ck6Uj1LIRR7M1bMW51U+k3BFGsRR5MVgMQmQVsfX8xdektnFavkTh1BNhTdol89WOtI/xV8xTvkANFPdhTWIkHFFe60dyJGDBV7xKGSTJlkc/FDRxQRlEZFFFWCQftVb7W69M9TTRwVu7QQYUuEFAwBQm9k9SFOCBXJ5LVxRZRVI+S2o1qbR0UU4hJPWBQK80BOJJiCW81NJVU5xeTVb9TmMUEKFMiTW1tHQhUP1V20AjFfvEd8RK4RX8xXHEMOFOdxUd5OSjV3tbGl2sT8AUXBFd7056ZCqSRJkk49FdDFyaWLtKRBSbQkPBFNISRQs0DKlTX1PpUpxMThRUAVQ6RbEU1IFKfVUg9BhBXVxD7xVb5LoRWStST0NXFBuDXm9ca0EoFL2BSn4VY7X01BvTQHYUWQJLExUmtWi0xkFQ7kj7RX2lnKSpQVBrVKtHJFTe4UhXFHIhVdxfXkT3JEJBRS5E9gNClhU85GETS6sUMlFdrFErVG9Uq1ycTzoUbgFHYRTXMVQdT44UjjFEGxU/xORiTB0lrOVvtb60MiJE0xSQIUo7JQL1fKQYQVRNTnEV/rQugVgtRrYlwtV1xY/ksJFMHhSRUVAuTa0UhqFcbEV1FQPU4eJU3ldMUZ5Y21auT5IUFrNFSkQE4VxrUh1OJCRjUlzuTcA0D1NAZhXp9ApjRMREaTFN9BTdAUezFMwRQcAUXeFL4BSXgVk/TFIVaLRPIVrPQcQV/8WbtbXFYdTTsVssUuxfjF89UTs=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="91" id="controllerType=0 controllerNumber=1 scan=92" defaultArrayLength="44"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="334.91426755890711" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="8553.9755859375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="72825.0078125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="108.71043217664037" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="400.87438685299247" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.92.92.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=92""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.815671666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 402.17@cid35.00 [100.00-415.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="402.17161857439851" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="100.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="415.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=91"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="402.16705806088464" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="402.17161857439851" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1.183111953125e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="248"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXLF7+AAAADVd41/0///f6hbnbGTDcWJ41odgOPPWFEGsw6b4YsMOEkmdaXRhQWUgabytSnFAsFgwg8XEQAxqX7hUWmyMDqSm2EPbU8O4PqEj7EMYJh60T3l2TmstAzZHRa32XVBXeHfS5tBDOkrqVTXtBCL7wMBAXPuH+vc/cPEi1EsnW9ZzBkAqYKcruHugxIRSGmqaSm8I+n/Su+SleuiIwMp2t4/gBtCEJqpOjzLdetBAiCroA==</binary> </binaryDataArray> <binaryDataArray encodedLength="124"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XOFR8VvCW/Fb8VTBV6FS0VWxUdFSAlThXRtX4lnhUHpQY14IRkkUSMFX0VsSVpJTYlWhV1JWx0gVFTVkphJawVz6QTUVAFUuFRAlUCU5hWklqUW1NWQlRdU4gA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="92" id="controllerType=0 controllerNumber=1 scan=93" defaultArrayLength="55"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="365.10511726294499" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.6593634375e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.318000625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="109.7372801337752" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="416.21018165075361" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.93.93.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=93""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.858675" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 433.10@cid35.00 [105.00-445.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="433.0922908204854" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="105.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="445.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=91"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="433.09683180289215" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="433.0922908204854" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="82847.265625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="300"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QW/1/2AAAABEcZptiv//f5cU/SCeyKoeAl2BICB3Pb79HftwcRCliVIVG8WDk2Cv3ZnLaEoqgKoxEWzWmXP/RWEyzxepOQt1kdZxUKlA5t4wTKplQQJUxo7hIgbSaRIFoHFlYr8ZqVaw4ZT07NmLsQtDhReJXgE54iAHiZLllU0V+TEmIaScudIjBMlU4j7Ry7YPuSRV4DtYZeOJtBGlkd/5Dg5uAhcAgZsWRj4TOuCXk82NSaMI2dERfHOZfeKuUmHy7KIQhDKaiPyhiIxKMMhuL9+rwKq1YIEKyUB64A==</binary> </binaryDataArray> <binaryDataArray encodedLength="152"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VdFVIl7RXqFSsVrUVpFYAlUCV9FQsV3BWYNUUlBiXFRZU1OfXPFVwVCKVEpVk1hiVmNR4VrhVLFQl1cSUqNQcluUXLZTFFrDQRoV9EWXRWU0zrEwOIJc5VKSX5JUAlFTXcVcs1iCWuNNAhUGNWVFwSA=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="93" id="controllerType=0 controllerNumber=1 scan=94" defaultArrayLength="45"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="381.07927409016878" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="26694.951171875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.246915625e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="121.72175057024782" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="459.97400890940492" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.94.94.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=94""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.902511666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 449.06@cid35.00 [110.00-460.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="449.05690463373588" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="110.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="460.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=91"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="449.05672397085203" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="449.05690463373639" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="41873.5546875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="252"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QXCtv3AAAADVkuJ+sf//f58fiP4BlJdWGbiXkNmRzpkBb8u7yR7Bb8l5km8qgnLXH7kSoaJwftDezsyRldnKFZBe18eUza3dGT9+Np9rSYQcHbSMkdYJmBJSwnidcYaumkaLKBZD/wORC0LJCovdESAoQUC+kkudo5bQRC4aVpZDnqKCLqrw4cpIOgUSdpjckLxIg51iPf4hi236WZZAPG3RAJgPYBl+dzLJWmdmQW45ZHmcxGTB0y4ZsA==</binary> </binaryDataArray> <binaryDataArray encodedLength="128"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WbFQ0VvxWMFekkoHFXMlgpVrZZ8VeRUQNVw1a7UkRblEO5NWs19XVANQI1wSWtNCFBXAJBvzVTRWxkdIZS8VWEVcFdpF4DXRJR21MGSFcVaRVFJHhyWQ9dsVHhV9EA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="94" id="controllerType=0 controllerNumber=1 scan=95" defaultArrayLength="33"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="539.02842526213647" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="17006.7578125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="39832.94140625"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="157.44509154119507" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1720.9190127058118" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.95.95. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=95""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.949511666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 585.33@cid35.00 [150.00-1770.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="150.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1770.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=91"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="585.32564197339593" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="585.32564197339593" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="39615.60546875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="188"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVONIsAAAAA4CBkwP3IdNR+lk0GSpeHpLF58OlPPChJkSMWdi3CcA4W0UBlZwP05YuyT4XUu21mc3uKBH0lqumF+ERTMlBUHtHEe4bU6zSpadhScPMyNqY7WweXUDIEGR1RhVdx4OQBV9AP6+UDj7M2RDF5zYSAce40sDDYP+UBEjnLTDrnwcIm5GhGA</binary> </binaryDataArray> <binaryDataArray encodedLength="92"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XHFcsVMSU7FRa16CVdFa4V/RVJJWAldiVwNV4V90U0RbBF6xT2JF1iV2ZSslEiXOFTAleSUSJU4VazUDJZ0VbxXzIA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="95" id="controllerType=0 controllerNumber=1 scan=96" defaultArrayLength="40"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="357.97379125630994" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="12985.1171875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="35782.109375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="109.2521610018627" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1223.5365199842547" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.96.96. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=96""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="3.99468" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 406.14@cid35.00 [100.00-1230.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="100.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1230.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=91"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="406.13702901968742" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="406.13702901968742" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="24433.109375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="236"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWNSHOAAAAAXrPZBJrJHRiUri6lokqbpw2O72ZqHL+D8PlyRmmKb4px5uEMXAadake1cph0snpuYZBwFHJ5gAQgzbngQHLoAng78luMQloLGjh9vKUSSr3jLEc7ew5jld26YkrPNqPSGsVcughEFcmFpyoo1kREgG1noJueQL2sdcwBrXjvA9tfakg32VAXQlSNL0QBDl+cQqCTWTgXvCmQ5OFk4QEP4RvsIZuEfcA==</binary> </binaryDataArray> <binaryDataArray encodedLength="108"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XYFcIVAhWEFcMVUxUhJSBlWBX2FfkVIxUYFWYVXDVTFcslSCVbJYoVpRSbI1GmXWFVvVBhV3NSYVuBWMFd4VshUIFeUVNBVWFb0VvRXGFcsw</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="96" id="controllerType=0 controllerNumber=1 scan=97" defaultArrayLength="266"> <cvParam cvRef="MS" accession="MS:1000579" name="MS1 spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="1"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="664.11558007376834" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.1382175e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="1.903784875e06"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="400.98223518515158" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1694.3492990759617" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.97.97. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=97""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.039458333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI Full ms [400.00-1700.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="1"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="83.084716796875" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="400.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1700.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="1288"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="808"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="97" id="controllerType=0 controllerNumber=1 scan=98" defaultArrayLength="24"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="524.05705765281323" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="1.2128528125e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="2.631344375e05"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.276609848394" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="618.05792121248214" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.98.98.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=98""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.064006666667" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 664.12@cid35.00 [170.00-675.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="2"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="664.11564110840675" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="170.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="675.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=97"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="664.11479150623643" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="664.11564110840675" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="1.1382175e05" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="140"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWRrkMAAAACQBkB9hf//fykBYiG7C0Xh7SD28WUWTtDmPWHtm4nlFwqlK8kQ0X3bzhZ96GwNHPas4SUoCJobmbaRNbdkHRcp4R6YQMWb4IZYo3/gwXBfNbEJt7YRf4AVgCUsv64qyxFA</binary> </binaryDataArray> <binaryDataArray encodedLength="72"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UXRfc1wCRbAVzxUVJZoVBCX51fA1JyVZJWsTXJ0UeRRY8jFncUpFJVAl/hW2Je0V9DUAMA==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="98" id="controllerType=0 controllerNumber=1 scan=99" defaultArrayLength="17"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="664.11521386593586" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="43317.078125" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="64552.25"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="196.27418371868069" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="690.5693277991553" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.99.99.1 File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=99""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.106925" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 723.17@cid35.00 [185.00-735.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="3"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="723.16367083806676" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="185.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="735.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=97"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="723.16417620220136" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="723.16367083806654" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000041" name="charge state" value="1"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="24143.326171875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="108"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWOMTSAAAAAtOeZ3j///f6aGZyFSLoVQ39TFoZCxZXUFWxatEPVfI00IEYgTEIBbPY4ds6xvlASSYQsNlyAQRAUa/pGhs9USqIBHqk9R0A==</binary> </binaryDataArray> <binaryDataArray encodedLength="48"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>WYdUwVYSVAJTklrxXLFREljxXnNcQ07CFdwUU5pI+hVcJXEg</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="99" id="controllerType=0 controllerNumber=1 scan=100" defaultArrayLength="44"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="406.05986527751588" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="11362.2529296875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="58798.1953125"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="115.4922810644822" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1361.4218353974072" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.100.100. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=100""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.15401" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 467.09@cid35.00 [115.00-1415.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="4"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="115.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1415.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=97"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="467.08661314387467" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="467.08661314387467" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="24085.708984375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="240"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QVmZmYAAAACsaDIuBUoIPpzAgLCpuY+xve6oGtv2axyV8qGe5nFNFcDzWBDFLMiavjjckMWHuimYXWkGE4hhjgtGaX68aZIqBoUVcUPxmY7+DhbMmLEYWxpRruUAUeKdfVl0EEu5VgBo2RJy9+r72wsq339KHBELtT+KKtveQQT/vUklrUOyAD52Hly2uZ3tHniZbME9FBJrRZ3NSY0TBG8UA2nif3Ahsbe7B4tqlxC//Sjd</binary> </binaryDataArray> <binaryDataArray encodedLength="120"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>XZFSE1vhXiJf4VjhXhJYIlcaX+FXAlnBUsFasVjxW6NQBEXiFQUlgyX2pRCFgSXgJaFlEvQmwlnmXyddclzFXIRTC1/xVbRW9FayVCJR8lPRVMFTEle2UXI=</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="100" id="controllerType=0 controllerNumber=1 scan=101" defaultArrayLength="36"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="559.12943418017574" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="16564.568359375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="55604.58984375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="165.61306157588157" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1935.4254351493453" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.101.101. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=101""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.199185" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 653.32@cid35.00 [165.00-1970.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="5"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="165.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1970.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=97"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="653.31488710364738" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="653.31488710364738" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="21177.466796875" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="200"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QUghLYAAAACiWjgfIZkuIBVzFaKYfSadnfMT3igpW8FIUW068l10mgHCTRxXAviTdmgIHGDIJRi3GPOVvlZHERS9MplPBjyom10raeqTy0FhOmuwSZEXGNEiRiYxIGgRGR2k/5t9C5sU/7oH/A4bUdWlltT+ehdmlL4Y+UP2n3ZkcQSD/pUQzaFoEQRI9IRQHfK0CA==</binary> </binaryDataArray> <binaryDataArray encodedLength="100"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>VNFQsVrhXwNQplcDX+FXsV2hXpRYMlDBU8Fc8VzRXTddBFt4SK0VojUeFctFpDWLdYeFmDRbBFjmXOJX8VVSUAJQQlJFXwdQ8Q==</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> <spectrum index="101" id="controllerType=0 controllerNumber=1 scan=102" defaultArrayLength="30"> <cvParam cvRef="MS" accession="MS:1000580" name="MSn spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000511" name="ms level" value="2"/> <cvParam cvRef="MS" accession="MS:1000130" name="positive scan" value=""/> <cvParam cvRef="MS" accession="MS:1000127" name="centroid spectrum" value=""/> <cvParam cvRef="MS" accession="MS:1000504" name="base peak m/z" value="522.06323915660153" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000505" name="base peak intensity" value="3009.042724609375" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <cvParam cvRef="MS" accession="MS:1000285" name="total ion current" value="18604.8984375"/> <cvParam cvRef="MS" accession="MS:1000528" name="lowest observed m/z" value="187.03404745485633" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000527" name="highest observed m/z" value="1697.6776390717878" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000796" name="spectrum title" value="Rpal_01.102.102. File:"Rpal_01.RAW", NativeID:"controllerType=0 controllerNumber=1 scan=102""/> <scanList count="1"> <cvParam cvRef="MS" accession="MS:1000795" name="no combination" value=""/> <scan> <cvParam cvRef="MS" accession="MS:1000016" name="scan start time" value="4.242038333333" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <cvParam cvRef="MS" accession="MS:1000512" name="filter string" value="FTMS + c NSI d Full ms2 616.25@cid35.00 [155.00-1860.00]"/> <cvParam cvRef="MS" accession="MS:1000616" name="preset scan configuration" value="6"/> <cvParam cvRef="MS" accession="MS:1000927" name="ion injection time" value="1000.0" unitCvRef="UO" unitAccession="UO:0000028" unitName="millisecond"/> <userParam name="[Thermo Trailer Extra]Monoisotopic M/Z:" value="0" type="xsd:float"/> <scanWindowList count="1"> <scanWindow> <cvParam cvRef="MS" accession="MS:1000501" name="scan window lower limit" value="155.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000500" name="scan window upper limit" value="1860.0" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </scanWindow> </scanWindowList> </scan> </scanList> <precursorList count="1"> <precursor spectrumRef="controllerType=0 controllerNumber=1 scan=97"> <isolationWindow> <cvParam cvRef="MS" accession="MS:1000827" name="isolation window target m/z" value="616.24525755622312" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000828" name="isolation window lower offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000829" name="isolation window upper offset" value="2.5" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> </isolationWindow> <selectedIonList count="1"> <selectedIon> <cvParam cvRef="MS" accession="MS:1000744" name="selected ion m/z" value="616.24525755622312" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <cvParam cvRef="MS" accession="MS:1000042" name="peak intensity" value="20873.712890625" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> </selectedIon> </selectedIonList> <activation> <cvParam cvRef="MS" accession="MS:1000133" name="collision-induced dissociation" value=""/> <cvParam cvRef="MS" accession="MS:1000045" name="collision energy" value="35.0" unitCvRef="UO" unitAccession="UO:0000266" unitName="electronvolt"/> </activation> </precursor> </precursorList> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="184"> <cvParam cvRef="MS" accession="MS:1000521" name="32-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1002312" name="MS-Numpress linear prediction compression" value=""/> <cvParam cvRef="MS" accession="MS:1000514" name="m/z array" value="" unitCvRef="MS" unitAccession="MS:1000040" unitName="m/z"/> <binary>QWTedgAAAAC9sPl5SP//f5vNaQoSl/CyCV0nPRDHSntOKYDaWZ5/yrHuDVEwHPGaIQJmeyrgFXKe8gt4lFvR5lLzOQObizAKqvbxDY0iIen+BobanHOICPgHdRDpyLe+C/mELxAYRK0OE3kk7QELot0g0OUcJAtkCjywclB8NgpEW4MgVlLZ6g==</binary> </binaryDataArray> <binaryDataArray encodedLength="80"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>UFFeJlXBXpFZUVWBVoFWUVdRVuFTQV0xXEFVkVVzUaFWElJEXUJaAlHLWwNZQ1dxX6FSgVKhUvJf4l1h</binary> </binaryDataArray> </binaryDataArrayList> </spectrum> </spectrumList> <chromatogramList count="1" defaultDataProcessingRef="pwiz_Reader_Thermo_conversion"> <chromatogram index="0" id="TIC" defaultArrayLength="2436"> <cvParam cvRef="MS" accession="MS:1000235" name="total ion current chromatogram" value=""/> <binaryDataArrayList count="2"> <binaryDataArray encodedLength="25984"> <cvParam cvRef="MS" accession="MS:1000523" name="64-bit float" value=""/> <cvParam cvRef="MS" accession="MS:1000576" name="no compression" value=""/> <cvParam cvRef="MS" accession="MS:1000595" name="time array" value="" unitCvRef="UO" unitAccession="UO:0000031" unitName="minute"/> <binary>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</binary> </binaryDataArray> <binaryDataArray encodedLength="11176"> <cvParam cvRef="MS" accession="MS:1000519" name="32-bit integer" value=""/> <cvParam cvRef="MS" accession="MS:1002313" name="MS-Numpress positive integer compression" value=""/> <cvParam cvRef="MS" accession="MS:1000515" name="intensity array" value="" unitCvRef="MS" unitAccession="MS:1000131" unitName="number of detector counts"/> <binary>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</binary> </binaryDataArray> </binaryDataArrayList> </chromatogram> </chromatogramList> </run> </mzML> <indexList count="2"> <index name="spectrum"> <offset idRef="controllerType=0 controllerNumber=1 scan=1">4429</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=2">9026</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=3">14647</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=4">20306</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=5">25879</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=6">31516</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=7">37051</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=8">42030</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=9">47603</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=10">53188</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=11">58751</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=12">64312</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=13">69888</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=14">75200</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=15">80755</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=16">86380</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=17">91945</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=18">97611</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=19">103108</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=20">108092</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=21">113692</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=22">119152</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=23">124667</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=24">130205</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=25">135659</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=26">140890</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=27">146505</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=28">152115</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=29">157737</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=30">163331</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=31">168935</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=32">174156</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=33">179692</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=34">185272</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=35">190747</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=36">196220</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=37">201755</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=38">207273</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=39">212922</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=40">218491</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=41">224068</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=42">229635</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=43">235170</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=44">240528</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=45">245952</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=46">251406</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=47">256936</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=48">262420</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=49">267912</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=50">273192</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=51">278835</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=52">284374</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=53">289935</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=54">295575</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=55">301058</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=56">306568</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=57">312121</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=58">317586</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=59">323053</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=60">328571</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=61">334085</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=62">339803</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=63">345256</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=64">350733</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=65">356202</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=66">361686</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=67">367162</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=68">372809</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=69">378461</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=70">383954</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=71">389394</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=72">394962</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=73">400463</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=74">405694</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=75">411448</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=76">417099</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=77">422733</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=78">428316</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=79">433928</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=80">439244</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=81">444969</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=82">450575</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=83">456256</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=84">462082</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=85">467789</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=86">475700</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=87">481530</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=88">487281</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=89">493011</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=90">498705</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=91">504332</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=92">510494</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=93">516330</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=94">522233</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=95">528074</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=96">533704</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=97">539387</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=98">545154</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=99">550823</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=100">556425</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=101">562135</offset> <offset idRef="controllerType=0 controllerNumber=1 scan=102">567788</offset> </index> <index name="chromatogram"> <offset idRef="TIC">573525</offset> </index> </indexList> <indexListOffset>611925</indexListOffset> <fileChecksum>f6cdf7e6c379dfe7b91b25a6c61099502d6fba3b</fileChecksum> </indexedmzML>